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  • Nd:GdVO4 Laser Crystal
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  • Nd:GdVO4 Laser Crystal

Nd:GdVO4 Laser Crystal

Nd:GdVO4 Laser Crystal is an excellent laser crystal with similar properties to Nd: YVO4. It has excellent physical, optical, and mechanical properties. It is one of the ideal laser working materials for laser diode-pumped all-solid-state (DPSS) micro la
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  • Description
Nd: GdVO4 Laser Crystal
Neodymium doped gadolinium vanadate crystal (Nd: GdVO4) is an excellent laser crystal with similar properties to Nd: YVO4. It has excellent physical, optical, and mechanical properties. It is one of the ideal laser working materials for laser diode-pumped all-solid-state (DPSS) microlasers. Nd: GdVO4 has higher slope efficiency than Nd: YAG and its absorption cross-section is about 2 times that of Nd: YVO4 and 7 times that of Nd: YAG. Nd: GdVO4 at 1.06 μ The emission cross-section of M is larger than that of Nd: YAG, at 1.34 μ The emission cross-section of M is also higher than that of Nd: YAG. In particular, its thermal conductivity along the < 110 > direction is much higher than that of Nd: YVO4, which is equivalent to that of Nd: YAG. Nd: GdVO4 can achieve high concentration doping without luminescence concentration quenching. The large segregation coefficient also makes it relatively easy to grow Nd: GdVO4 crystals with high optical quality and uniform. Therefore, in the case of high-power DPSS, the effect of using Nd: GdVO4 is better than that of using Nd: YAG and Nd: YVO4.
Main advantages of Nd: GdVO4 crystal:
• large excited emission cross-section
• large absorption coefficient, wide absorption bandwidth, and little dependence on pump wavelength
• good thermal conductivity
• low laser threshold and high laser output slope efficiency
• high laser damage threshold
• good polarization of laser output
The company now has the large-scale production capacity of large-size and high-quality Nd: GdVO4 crystal, and can provide a concentration range: 0.1-3%. Customers at home and abroad are warmly welcomed to contact and negotiate with us. See the following table for the basic characteristics of the crystal
Specifications of Nd: GdVO4
Crystal Structure Tetragonal
Space Group I41/amd
Lattice Parameter a=0.721nm,b=0.635nm
Lasing Transition 4F3/2 ----> 4I11/2
Lasing Wavelength 1062.9nm
Emission Cross Section(at 1064nm) 7.6×10-19 cm2
Absorption Cross Section(at 808nm) 4.9×10-19 cm2
Absorption Coefficient(at 808nm) 74 cm-1
Index of Refractivity(at 1064nm) no=1.972,ne=2.192
Thermal Conductivity(<110>) 11.7 W/(m×K)
Density 5.47 g/cm3
Nd Dopant level (atomic) 0.1%,0.2%,0.3%,0.5%,0.7%,1.0%,...

Material Properties: Comparing Nd:GdVO4 and Nd:YVO4

Crystal Nd:GdVO4 Nd:YVO4
Crystal Structure,Space Group Tetragonal, I41/amd Tetragonal, I41/amd
Lattice constants(nm) a:0.721     b:0.635        a:0.721     b:0.629        
Melting temperature(℃) 1780 1825
Thermal expansion @25℃,×10-6/℃   a 1.5 a 4.43
b 7.3 b 11.4
Specific heat @25℃,cal/mol·K 32.6 24.6
dn/dT,×10-6/℃ 4.7 2.7

Information Regarding Neodymium Laser Host Crystals

Crystal Nd: YVO4 Nd: GdVO4 Nd: YAG
Laser Wavelength 1064.3nm,1342.0nm       1062.9nm,1340nm       1064.2nm,1338.2nm      
Emission bandwidth 0.8nm No data 0.45nm
(linewidth at 1064 nm)
Effective laser cross-section 15.6×10-19 cm2 7.6×10-19 cm2 6.5×10-19 cm2
(emission cross-section at 1064 nm)
Polarization Parallel to c-axis Parallel to c-axis unpolarized
Radioactive lifetime (microseconds) ~100μs ~95μs 230μs
at 1% Nd doping
Pump wavelength 808.5nm 808.4nm 807.5nm
Peak pump absorption at 1% doping ~41 cm-1 ~57 cm-1 /
Thermal conductivity, W/m/K 5.1 11.7 14
Doping concentration range 0.1-3.0% 0.1-3.0% 0.1-2.0%
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